First Steps:

Open a shell as root on Kali:

arp-scan --localnet | grep -i MAC_ADDRESS_OF_MACHINE

Here are the results of my arp-scan:

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Nmap:

nmap -sC -sV IP_ADDRESS_OF_TARGET_VM

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Here we have a web server on port 80. Nmap is telling us that the default webpage redirects to http://cms.icsi.vuln.

First, check it out by going to the IP Address of the VM in your Web Browser.

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